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Back in May, I made a fancy pants guide for the laser cutter at
ThingTank. It covers all the basics of vector graphics and the specific basics of the VersaLaser. I originally designed the booklet to be printed out. Just this week, I finally got around to tidying the manual into a digital-friendly version. It's a little specific to the laser/environment at ThingTank, but also useful for looking at the basic ideas of vector graphics and their relationship with lasers.
Download the booklet if you want.